A comparison of the figures-of-merit for nitrogen reduction on nitrogenase, solid electrodes and homogeneous catalysts
DOI: 10.14469/hpc/8243 Metadata
Created: 2021-05-22 18:44
Last modified: 2021-06-17 13:21
License: Creative Commons: Public Domain Dedication 1.0
Funding: "O.W. ACKNOWLEDGES FUNDING FROM THE ENGINEERING AND PHYSICAL SCIENCES RESEARCH COUNCIL GRANT EP/S023259/1. I.E.L,S, ACKNOWLEDGES FUNDING FROM THE EUROPEAN RESEARCH COUNCIL (ERC) UN-DER THE EUROPEAN UNION'S HORIZON 2020 RE-SEARCH AND INNOVATION PROGRAMME (GRANT AGREE-MENT NO. 866402). I.E.L.S. AND R.J. ACKNOWLEDGE FUNDING FROM THE FARADAY INSTITU-TION (EP/3003053/1)." does not match any project, edit to fix. If the project is new it may not be in the system yet.
Co-author: Olivia Westhead Co-author: Rhodri Jervis
Description
This document estimates the operating potentials on the RHE scale, the turnover frequencies (TOF) and turnover numbers (TON) for four different electrochemical nitrogen reduction systems over a solid electrode, the Schrock homogeneous catalyst for nitrogen reduction5 and nitrogenase. An idealised target electrode is also considered. This formulation allows for greater ease of comparison between homogeneous systems, enzymes and solid electrodes.
Files
| Filename | Size | Type | Description |
|---|---|---|---|
| Westhead 2021 Figures of merit calculation.pdf | 280KB | application/pdf | Text |