Equilibrium 1+2b+3b@210K (b: R=Me).
DOI: 10.14469/hpc/7149 Metadata
Created: 2020-04-28 16:02
Last modified: 2020-04-29 10:05
License: Creative Commons: Public Domain Dedication 1.0
Funding: (none given)
Description
NMR spectra for an equilibrium between 1-mesityl-2,2,3-tris(2,4,6-triisopropylphenyl)-2H-trisilirene (1), 1,3-di-tert-butyl-4,4-dimethyl-4,5-dihydro-1H-1,3,2-diazasilol-3-ium-2-ide (2b) and 1',3'-di-tert-butyl-4',4'-dimethyl-1,3,4,4-tetrakis(2,4,6-triisopropylphenyl)spiro[bicyclo[1.1.0]tetrasilane-2,2'-[1,3,2]diazasilolidine] (3b). NOTE: Compound numberings in file names related to a now obsolete scheme and should be disregarded.
Files
| Filename | Size | Type | Description |
|---|---|---|---|
| 1+4b+5b_210K.zip | 11MB | application/zip | Bruker raw FID dataset |
| 1+4b+5b_210K.mnpub | 0 | chemical/x-mnpub | Mestrenova signature file for 1+4b+5b_210K.zip |
| 1+4b+5b_210K.mnova | 7MB | chemical/x-mnova | MestreNova raw FID + Spectra dataset |
| 1+4b+5b_210K.mnpub | 0 | chemical/x-mnpub | Mestrenova signature file for 1+4b+5b_210K.mnova |
| 1+4b+5b_210K_1H.jdx | 219KB | chemical/x-jcamp-dx | JCAMP spectrum, 1H |
| 1+4b+5b_210K_29Si.jdx | 276KB | chemical/x-jcamp-dx | JCAMP Spectrum, 29Si |
| 1.cdxml | 11KB | chemical/x-cdxml | Connection table for 1 |
| 4b.cdxml | 6KB | chemical/x-cdxml | Connection table for 2b |
| 5b.cdxml | 15KB | chemical/x-cdxml | Connection table for 3b |
Member of collection / collaboration
| DOI | Description |
|---|---|
| 10.14469/hpc/6782 | NMR Spectra: Equilibrium Formation of Stable All-Silicon Versions of 1,3-Cyclobutandiyl |
Subject Keywords
| Keyword | Value |
|---|---|
| inchi | InChI=1S/C54H80Si3/c1-30(2)42-24-45(33(7)8)52(46(25-42)34(9)10)56-55(51-40(20)22-39(19)23-41(51)21)57(56,53-47(35(11)12)26-43(31(3)4)27-48(53)36(13)14)54-49(37(15)16)28-44(32(5)6)29-50(54)38(17)18/h22-38H,1-21H3 |
| inchi | InChI=1S/C12H26N2Si/c1-10(2,3)13-9-12(7,8)14(15-13)11(4,5)6/h9H2,1-8H3 |
| inchi | InChI=1S/C72H118N2Si4/c1-42(2)54-33-58(46(9)10)66(59(34-54)47(11)12)75(67-60(48(13)14)35-55(43(3)4)36-61(67)49(15)16)76(68-62(50(17)18)37-56(44(5)6)38-63(68)51(19)20)77(75,69-64(52(21)22)39-57(45(7)8)40-65(69)53(23)24)78(76)73(70(25,26)27)41-72(31,32)74(78)71(28,29)30/h33-40,42-53H,41H2,1-32H3 |
| inchikey | JXSUZCJPTAEVSS-UHFFFAOYSA-N |
| inchikey | FRMGLBZAPIJGDQ-UHFFFAOYSA-N |
| inchikey | LAAUGLZLOOXLTJ-UHFFFAOYSA-N |