Equilibrium Formation of Stable All-Silicon Versions of 1,3-Cyclobutandiyl
DOI: 10.14469/hpc/6773 Metadata
Created: 2020-02-10 11:49
Last modified: 2024-10-24 09:39
License: Creative Commons: Public Domain Dedication 1.0
Funding: (none given)
Co-author: Akin Azizoglu Co-author: Cem Burak Yildiz Co-author: Christopher Kay Co-author: David Scheschkewitz Co-author: Kinga I. Leszczyńska Co-author: Sandra Gonzalez Gallardo Co-author: Till Biskup
Description
Main group analogues of cyclobutane-1,3-diyls attract considerable interest due to their unique reactivity and electronic properties. So far only heteronuclear examples have been isolated. Here we report the isolation and characterization of all-silicon 1,3-cyclobutandiyls as stable closed-shell singlet species from the reversible reactions of cyclotrisilene c-Si3Tip4 (Tip = 2,4,6-triisopropylphenyl) with the N-heterocyclic silylenes c [(CR2CH2)(NtBu)2]Si: (R = H or methyl) with saturated backbones. At elevated temperatures, tetrasilacyclobutenes are obtained from these equilibrium mixtures. The corresponding reaction with an unsaturated N-heterocyclic silylene c-(CH)2(NtBu)2Si: proceeds directly to the corresponding tetrasilacyclobutene without detection of the assumed 1,3-cyclobutandiyl intermediate.
Members
| DOI | Description |
|---|---|
| 10.14469/hpc/6784 | Crystal structures: Equilibrium Formation of Stable All-Silicon Versions of 1,3-Cyclobutandiyl |
| 10.14469/hpc/6798 | FAIR Data Table: Equilibrium Formation of Stable All-Silicon Versions of 1,3-Cyclobutandiyl |
| 10.14469/hpc/6783 | Gaussian Calculations: Equilibrium Formation of Stable All-Silicon Versions of 1,3-Cyclobutandiyl |
| 10.14469/hpc/6782 | NMR Spectra: Equilibrium Formation of Stable All-Silicon Versions of 1,3-Cyclobutandiyl |
Associated DOIs
| Current dataset ... | DOI | Description |
|---|---|---|
| References | 10.1002/anie.202006283 | Journal article |
| isReferencedBy | 10.1002/anie.202006283 | Journal article |