Ethyl (2-phenylpropan-2-yl) malonate
DOI: 10.14469/hpc/6468 Metadata
Created: 2019-12-12 09:46
Last modified: 2020-03-21 07:31
License: Creative Commons: Public Domain Dedication 1.0
Funding: (none given)
Description
Ethyl malonyl chloride (234mg, 1.56mmole) was added in one go to a stirred solution of cumyl acohol (227mg, 1.67mmole) and N,N-dimethylaniline (164mg, 1.36mmole) in diethyl ether (2ml). The reaction was exothermic and the mixture went cloudy. After stirring at room temperature over the weekend, the supernatant of the reaction was applied to a column of silica gel and the product eluted with hexane : ethyl acetate (5 : 1) as a sweet-smelling, colourless oil (248mg).
Files
| Filename | Size | Type | Description |
|---|---|---|---|
| Cumyl_ethyl_malonate.jdf | 550KB | chemical/x-jeol-jdf | Jeol 400 MHZ 1H NMR Dataset |
| Cumyl_ethyl_malonate.mnpub | 0 | chemical/x-mnpub | Mestrenova signature file for Cumyl_ethyl_malonate.jdf |
| Cumyl_ethyl_malonate.mnova | 326KB | chemical/x-mnova | MestreNova Dataset |
| Cumyl_ethyl_malonate.mnpub | 0 | chemical/x-mnpub | Mestrenova signature file for Cumyl_ethyl_malonate.mnova |
| Cumyl_ethyl_malonate.jdx | 132KB | chemical/x-jcamp-dx | JCAMP-DX Dataset |
| Cumyl_ethyl_malonate.cdxml | 9KB | chemical/x-cdxml | Chemdraw descriptor for molecule |
Member of collection / collaboration
| DOI | Description |
|---|---|
| 10.14469/hpc/6215 | 1st Year undergraduate synthesis 1.2 laboratory (2019-2020) |
Associated DOIs
| Current dataset ... | DOI | Description |
|---|---|---|
| isReferencedBy | 10.5281/ZENODO.3722797 | Ethyl (2-phenylpropan-2-yl) malonate |
Subject Keywords
| Keyword | Value |
|---|---|
| inchi | InChI=1S/C14H18O4/c1-4-17-12(15)10-13(16)18-14(2,3)11-8-6-5-7-9-11/h5-9H,4,10H2,1-3H3 |
| inchikey | KKOOECZDSKSVIG-UHFFFAOYSA-N |