User-Friendly Copper-Catalysed Reduction of Azides to Amines
DOI: 10.14469/hpc/6099 Metadata
Created: 2019-09-16 11:42
Last modified: 2024-11-27 17:05
License: Creative Commons: Public Domain Dedication 1.0
Funding: (none given)
Co-author: Andrew White
Description
Three homoleptic copper(I) complexes have been prepared and applied to the reduction of organic azides. Under optimised conditions, complex [Cu(HPDIDMA)2]BF4 3 (HPDIDMA = 2,6-bis[N-(4-dimethylaminophenyl)carbaldimino]pyridine) could reduce a range of electron-poor azides in a mixture of DMSO and water without the need of an additional H-source.
Members
| DOI | Description |
|---|---|
| 10.14469/hpc/6100 | Cu-PDI reduction of azides - NMR Data |
| 10.14469/hpc/6101 | Cu-PDI reduction of azides - Crystallographic Data |
Associated DOIs
| Current dataset ... | DOI | Description |
|---|---|---|
| References | 10.1002/ajoc.201900555 | Published reference |