Preparation and Characterisation of Heterobimetallic Copper---Tungsten Hydride Complexes

DOI: 10.14469/hpc/4078 Metadata

Created: 2018-04-18 19:09

Last modified: 2018-05-10 01:59

Author: Alexandra Hicken

License: Creative Commons: Public Domain Dedication 1.0

Funding: (none given)

Co-author: Andrew White
Co-author: Mark Crimmin


The preparation and structural characterisation of three new heterobimetallic hydride complexes containing 3-centre,2-electron W–H–Cu bonds is reported. These complexes have been characterised by single crystal X-ray crystallography and multinuclear NMR spectroscopy. The bonding in these complexes has been analysed by DFT calculations.


10.14469/hpc/4140 1•W
10.14469/hpc/4141 2•W
10.14469/hpc/4142 3•W
10.14469/hpc/4143 X-Ray Coordinates