Ammonide: an alkalide formed from ammonia.
DOI: 10.14469/hpc/3455 Metadata
Created: 2017-12-17 08:29
Last modified: 2017-12-19 12:03
License: Creative Commons: Public Domain Dedication 1.0
Funding: (none given)
Description
Alkalides are anionic alkali compounds such as  sodide (Na-), kalide (K-), rubidide (Rb-) or caeside (Cs-). Around 90 examples can be found in the Cambridge structure database (See DOI: 10.14469/hpc/3453 for the search query and results). So what about the ammonium analogue,  ammonide (NH4-)? A quick search of Scifinder drew a blank!  So here  I take a look at this intriguing simple little molecule.
Member of collection / collaboration
| DOI | Description |
|---|---|
| 10.14469/hpc/3268 | Hyper-chemistry: -valency, -bonds, -coordination and -data (FAIR). |
Members
| DOI | Description |
|---|---|
| 10.14469/hpc/3457 | Ammonide, NH4(-). Def2-TZVPPD, WFN |
| 10.14469/hpc/3454 | Ammonium, NH4(+), Def2-TZVPPD |
| 10.14469/hpc/3456 | Ammonide, NH4(-). Def2-TZVPPD, NBO |
| 10.14469/hpc/3458 | NH4(+) Def2-TZVPPD/water Wiberg |
| 10.14469/hpc/3453 | A search for crystal structures of alkalides. |
| 10.14469/hpc/3460 | Ammonide, NH4(-). Def2-TZVPPD, TS for dissociation |
| 10.14469/hpc/3461 | Ammonide, NH4(-). Def2-TZVPPD, RP for dissociation |
| 10.14469/hpc/3462 | Ammonide, NH4(-). Def2-TZVPPD, IRC for dissociation |
| 10.14469/hpc/3464 | Ammonide, NH4(-). Def2-TZVPPD, IRC for dissociation, ultra-fine pathway |
| 10.14469/hpc/3465 | Ammonide, NH4(-). Def2-QZVPPD, NBO |
| 10.14469/hpc/3466 | Ammonide, NH4(-). Def2-QZVPPD, WFN |
| 10.14469/hpc/3470 | OH4 Def2-QZVPPD NBO |
Associated DOIs
| Current dataset ... | DOI | Description |
|---|---|---|
| References | 10.14469/hpc/3372 | Blog posts: Expanded Rydberg-shell Hypervalency |
| References | 10.14469/hpc/3459 | Blog post: Ammonide: an alkalide formed from ammonia and resembling an electride. |