Ionic model for general acid catalysed decarboxylation

DOI: 10.14469/hpc/204 Metadata

Created: 2016-01-10 08:33

Last modified: 2019-03-29 09:41

Author: Henry Rzepa

License: Creative Commons: Public Domain Dedication 1.0

Funding: (none given)

Co-author: Charles ROMAIN
Co-author: Matthew Harvey

Description

A quantum model for the general acid catalysed decarboxylation of indole-3-carboxylic acid

Files

FilenameSizeTypeDescription
indole-carboxylate.cdx 4KB chemical/x-cdx Chemical structure
isotope.dat 69KB application/octet-stream kinetic isotope effects, input file
isotope.out 100KB application/octet-stream kinetic isotope effects, output file

Member of collection / collaboration

DOIDescription
10.14469/hpc/178 Mechanism and kinetic isotope effects for protiodecarboxylation of indoles.

Associated DOIs

Current dataset ...DOIDescription
References 10.1039/P29770000281 Heteroaromatic hydrogen exchange reactions. Part 9. Acid catalysed decarboxylation of indole-3-carboxylic acids
References 10.14469/spiral/20860 PhD thesis. Hydrogen transfer reactions of Indoles
References 10.5281/zenodo.19272 KINISOT. A basic program to calculate kinetic isotope effects using normal coordinate analysis of transition state and reactants.

Subject Keywords

KeywordValue
inchi InChI=1S/C9H7NO2/c11-9(12)7-5-10-8-4-2-1-3-6(7)8/h1-5,10H,(H,11,12)
inchikey KMAKOBLIOCQGJP-UHFFFAOYSA-N

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