σ or π nucleophilic reactivity of imines

DOI: 10.14469/hpc/1743 Metadata

Created: 2016-10-03 14:12

Last modified: 2016-10-11 12:48

Author: Henry Rzepa

License: Creative Commons: Public Domain Dedication 1.0

Funding: (none given)

Description

A series of blog posts exploring the mechanism and reactivity of imines, here the response to substituents.

Member of collection / collaboration

DOIDescription
10.14469/hpc/177 Computation data for Henry Rzepa's blog

Members

DOIDescription
10.14469/hpc/1725 Imine + peracetic acid, N attack + H2O TS, t-Bu, p-NMe2Ph
10.14469/hpc/1728 Imine + peracetic acid, N attack + H2O TS, t-Bu, p-NO2Ph
10.14469/hpc/1722 Imine + peracetic acid, π-attack zwitterion + H2O TS, t-Bu, p-NO2Ph
10.14469/hpc/1744 Imine + peracetic acid, π attack zwitterion + H2O TS, t-Bu, p-NMe2Ph
10.14469/hpc/1753 Imine + peracetic acid, pi attack zwitterion + H2O TS, t-Bu, p-NMe2Ph + mCPBA CDCl3
10.14469/hpc/1752 Imine + peracetic acid, pi attack zwitterion + H2O TS, t-Bu, p-NO2Ph + mCPBA CDCl3
10.14469/hpc/1756 Imine + peracetic acid, N attack zwitterion + H2O TS, t-Bu, p-NMe2Ph + mCPBA CDCl3
10.14469/hpc/1745 Imine + peracetic acid, N attack zwitterion + H2O TS, t-Bu, p-NO2Ph + mCPBA CDCl3
10.14469/hpc/1762 Imine + peracetic acid, N attack zwitterion + H2O TS, t-Bu, p-NMe2Ph + mCPBA CDCl3 proton on N

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