Addition of CarbonâFluorine Bonds to a Mg(I)âMg(I) bond: An Equivalent of Grignard Formation in Solution
Created: 2016-10-02 13:01
Last modified: 2016-10-03 14:35
License: Creative Commons: Public Domain Dedication 1.0
Funding: (none given)
Addition of the carbonâfluorine bond of a series of perfluorinated and polyfluorinated arenes across the MgâMg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbonâmagnesium bond and a new fluorineâmagnesium bond and is analogous to Grignard formation in homogeneous solution. Instructions: NMR data for selected compounds X-Y. Version 11 of the Mestrenova software is required to process these files, available from http://mestrelab.com/software/mnova/download/ Download the .mnpub signature file and load it into MestreNova to view the spectra. To view datasets obtained here, Mestrenova need not be licensed.
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|References||10.1021/jacs.6b08104||Addition of CarbonâFluorine Bonds to a Mg(I)âMg(I) bond: An Equivalent of Grignard Formation in Solution - Manuscript|