Addition of CarbonâFluorine Bonds to a Mg(I)âMg(I) bond: An Equivalent of Grignard Formation in Solution
DOI: 10.14469/hpc/1726 Metadata
Created: 2016-10-02 13:01
Last modified: 2016-10-03 14:35
License: Creative Commons: Public Domain Dedication 1.0
Funding: (none given)
Co-author: Andrew White Co-author: Mark Crimmin
Description
Addition of the carbonâfluorine bond of a series of perfluorinated and polyfluorinated arenes across the MgâMg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbonâmagnesium bond and a new fluorineâmagnesium bond and is analogous to Grignard formation in homogeneous solution. Instructions: NMR data for selected compounds X-Y. Version 11 of the Mestrenova software is required to process these files, available from http://mestrelab.com/software/mnova/download/ Download the .mnpub signature file and load it into MestreNova to view the spectra. To view datasets obtained here, Mestrenova need not be licensed.
Members
| DOI | Description |
|---|---|
| 10.14469/hpc/1731 | Compound 2b |
| 10.14469/hpc/1732 | Compound 2a |
| 10.14469/hpc/1733 | Compound 2c |
| 10.14469/hpc/1734 | Compound 2d |
| 10.14469/hpc/1735 | Compound 2e |
| 10.14469/hpc/1736 | Compound 2f |
| 10.14469/hpc/1737 | Compound 2g |
| 10.14469/hpc/1738 | Compound 2h |
| 10.14469/hpc/1739 | Compound 2i |
| 10.14469/hpc/1740 | Compound 2j |
| 10.14469/hpc/1741 | Compound 2k |
| 10.14469/hpc/1742 | Compound 4 |
Associated DOIs
| Current dataset ... | DOI | Description |
|---|---|---|
| References | 10.1021/jacs.6b08104 | Addition of CarbonâFluorine Bonds to a Mg(I)âMg(I) bond: An Equivalent of Grignard Formation in Solution - Manuscript |