Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) bond: An Equivalent of Grignard Formation in Solution
Created: 2016-10-02 13:01
Last modified: 2016-10-03 14:35
Addition of the carbon–fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg–Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon–magnesium bond and a new fluorine–magnesium bond and is analogous to Grignard formation in homogeneous solution. Instructions: NMR data for selected compounds X-Y. Version 11 of the Mestrenova software is required to process these files, available from http://mestrelab.com/software/mnova/download/ Download the .mnpub signature file and load it into MestreNova to view the spectra. To view datasets obtained here, Mestrenova need not be licensed.
|10.1021/jacs.6b08104||Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) bond: An Equivalent of Grignard Formation in Solution - Manuscript|