σ or π nucleophilic reactivity of imines? A mechanistic twist emerges.

DOI: 10.14469/hpc/1704 Metadata

Created: 2016-09-28 08:42

Last modified: 2016-09-28 09:32

Author: Henry Rzepa

License: Creative Commons: Public Domain Dedication 1.0

Funding: (none given)

Description

See Henry Rzepa's blog at <a href="http://www.ch.imperial.ac.uk/rzepa/blog/?p=16902">http://www.ch.imperial.ac.uk/rzepa/blog/?p=16902</a>

Member of collection / collaboration

DOIDescription
10.14469/hpc/177 Computation data for Henry Rzepa's blog

Members

DOIDescription
10.14469/hpc/1697 Imine + peracetic acid,N attack + H2O, TS
10.14469/hpc/1702 Imine + peracetic acid,N attack + H2O, TS IRC
10.14469/hpc/1700 Imine + peracetic acid, pi attack zwitterion + H2O IRC => C-O formation TS IRC
10.14469/hpc/1694 Imine + peracetic acid, pi attack zwitterion + H2O TS
10.14469/hpc/1691 Imine + peracetic acid, pi attack zwitterion + H2O TS IRC, oxaziridine product
10.14469/hpc/1703 Imine + peracetic acid, π attack zwitterion + H2O
10.14469/hpc/1693 Imine + peracetic acid, π attack zwitterion + H2O TS IRC
10.14469/hpc/1701 Imine + peracetic acid, pi attack + H2O, TS. IRC
10.14469/hpc/1695 Imine + peracetic acid, pi attack zwitterion + H2O reactant
10.14469/hpc/1692 Imine + peracetic acid, pi attack zwitterion + H2O IRC => C-O formation TS
10.14469/hpc/1690 Imine + peracetic acid, pi attack zwitterion + H2O TS IRC, addition int
10.14469/hpc/1698 Imine + peracetic acid, π attack + H2O, TS.
10.14469/hpc/1678 Imine + peracetic acid, π attack zwitterion + H2O TS IRC, addition int
10.14469/hpc/1696 Imine + peracetic acid, π attack zwitterion + H2O intermediate

Associated DOIs

Current dataset ...DOIDescription
References 10.14469/hpc/1705 σ or π nucleophilic reactivity of imines? A mechanistic twist emerges.

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