NMR Data for compound 38b. 2,4,6-tris(2-chlorophenyl)-1,3,5,2,4,6-trioxatriborinane in isolation
DOI: 10.14469/hpc/14849 Metadata
Created: 2024-11-09 14:02
Last modified: 2025-04-17 06:53
License: Creative Commons: Public Domain Dedication 1.0
Funding: (none given)
Description
Under an atmosphere of argon, 2-chlorophenyl boronic acid (3g, 19 mmol) was suspended in toluene (60 ml) and heated to reflux under a dean-stark apparatus for 4 hours. On cooling, a white precipitate formed. The reaction mixture was filtered under air and washed twice with toluene (10 ml), redissolving most of the solid. The solution was poured into ice cold hexane (150 ml) and a white precipitate formed, the solid was collected by filtration, washed with twice with hexane (20 ml), and dried under reduced pressure. Yield = 1.17 g white needle crystals, (2.8 mmol, 44 %).
Member of collection / collaboration
| DOI | Description |
|---|---|
| 10.14469/hpc/14846 | NMR Data for compound 38. Boroxine and boronic acid - amine complexes |
Members
| DOI | Description |
|---|---|
| 10.14469/hpc/14862 | NMR Data for Compound 38b. 2,4,6-tris(2-chlorophenyl)-1,3,5,2,4,6-trioxatriborinane. 1H |
| 10.14469/hpc/14863 | NMR Data for Compound 38b. 2,4,6-tris(2-chlorophenyl)-1,3,5,2,4,6-trioxatriborinane. 13C |
| 10.14469/hpc/14864 | NMR Data for Compound 38b. 2,4,6-tris(2-chlorophenyl)-1,3,5,2,4,6-trioxatriborinane. 11B |
Subject Keywords
| Keyword | Value |
|---|---|
| Inchi | InChI=1S/C18H12B3Cl3O3/c22-16-10-4-1-7-13(16)19-25-20(14-8-2-5-11-17(14)23)27-21(26-19)15-9-3-6-12-18(15)24/h1-12H |
| Inchikey | ZIRQCPUDORIPKP-UHFFFAOYSA-N |