NMR data for compound 34. N-(pyridin-2-yl)picolinamide

DOI: 10.14469/hpc/14744 Metadata

Created: 2024-11-02 07:05

Last modified: 2024-11-05 18:47

Author: Henry Rzepa

License: Creative Commons: Public Domain Dedication 1.0

Funding: (none given)

Description

Synthesised according to the general procedure, reaction time 42 hrs. Purified by flash column chromatography (EtOAc in hexanes, 10% à 100%). Yield = 200 mg white solid, 20%. Analytical data is in accordance with literature reports.21 1H NMR (700 MHz, CDCl3) δ (ppm) = 10.55 (s, 1H), 8.64 (ddd, J = 4.7, 1.6, 0.9 Hz, 1H), 8.42 (dt, J = 8.3, 0.8 Hz, 1H), 8.37 (ddd, J = 4.9, 1.9, 0.9 Hz, 1H), 8.30 (dt, J = 7.8, 1 Hz, 1H), 7.91 (td, J = 7.7, 1.7 Hz, 1H), 7.76 (m, 1H), 7.49 (ddd, J = 7.5, 4.7, 1.2 Hz, 1H), 7.08 (ddd, J = 7.3, 4.9, 1.0 Hz, 1H). 13C NMR (176 MHz, CDCl3) δ (ppm) = 162.8, 151.3, 149.5, 148.4, 148.4, 138.4, 137.7, 126.9, 122.6, 120.0, 114.1. HRMS [C11H9N3O+H]+ : Expected 200.0818, observed 200.0817 Melting point : 101 – 104 °C

Member of collection / collaboration

DOIDescription
10.14469/hpc/14635 Borate-Catalysed Direct Amidation Reactions of Coordinating Substrates. NMR data

Members

DOIDescription
10.14469/hpc/14813 NMR data for compound 34. N-(pyridin-2-yl)picolinamide. 1H
10.14469/hpc/14814 NMR data for compound 34. N-(pyridin-2-yl)picolinamide. 13C

Subject Keywords

KeywordValue
Inchi InChI=1S/C11H9N3O/c15-11(9-5-1-3-7-12-9)14-10-6-2-4-8-13-10/h1-8H,(H,13,14,15)
Inchikey JRYYQECAAAEQLX-UHFFFAOYSA-N

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