NMR data for compound 27. (S)-N-(1-phenylethyl)pivalamide

DOI: 10.14469/hpc/14737 Metadata

Created: 2024-11-02 06:56

Last modified: 2025-02-08 16:21

Author: Henry Rzepa

License: Creative Commons: Public Domain Dedication 1.0

Funding: (none given)

Description

Synthesised according to the general procedure. Purified by flash column chromatography (EtOAc 15 % à 60 % in cyclohexane). Yield = 763 mg white solid, 74%. Analytical data is in accordance with literature reports.18 1H NMR (700 MHz, CDCl3) δ (ppm) = 7.33 (t, J = 7.6 Hz, 2H), 7.29 (d, J = 7.4 Hz, 2H), 7.25 (t, J = 7.2 Hz, 1H), 5.82 (s, 1H), 5.10 (qn, J = 7.1 Hz, 1H), 1.48 (d, J = 6.9 Hz, 3H), 1.20 (s, 9H). 13C NMR (176 MHz, CDCl3) δ (ppm) = 177.6, 143.6, 128.8, 127.4, 126.16, 48.6, 38.7, 27.7, 21.9 HRMS [C13H19NO+H]+ : Expected 206.1539, observed 206.1535 Melting point: 118 – 119 °C

Member of collection / collaboration

DOIDescription
10.14469/hpc/14635 Borate-Catalysed Direct Amidation Reactions of Coordinating Substrates. NMR data

Members

DOIDescription
10.14469/hpc/14800 NMR data for compound 27. (S)-N-(1-phenylethyl)pivalamide. 13C.
10.14469/hpc/14799 NMR data for compound 27. (S)-N-(1-phenylethyl)pivalamide. 1H

Subject Keywords

KeywordValue
Inchi InChI=1S/C13H19NO/c1-10(11-8-6-5-7-9-11)14-12(15)13(2,3)4/h5-10H,1-4H3,(H,14,15)/t10-/m0/s1
Inchikey HBBKPRZFGXDWHG-JTQLQIEISA-N

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