NMR data for compound 3. N-benzylbenzamide

DOI: 10.14469/hpc/14636 Metadata

Created: 2024-10-02 10:15

Last modified: 2024-11-05 16:16

Author: Henry Rzepa

License: Creative Commons: Public Domain Dedication 1.0

Funding: (none given)

Co-author: Richard Procter

Description

Synthesised according to the general procedure, using 5 mol% or 2 mol% catalyst loading. Purified by flash column chromatography (EtOAc:Cyclohexane 30% à 60%). Analytical data in accordance with literature reports.5 Yield = 923 mg white solid, 4.37 mmol, 87% 1H NMR (700 MHz, CDCl3): δ (ppm) = 7.79 (d, J = 7.6 Hz, 2H), 7.50 (t, J = 7.3 Hz, 1H), 7.43 (t, J = 7.6 Hz, 2H), 7.36 (m, 4H), 7.33-7.28 (m, 1H), 6.46 (s, 1H), 4.65 (d, J = 5.6 Hz, 2H). 13C NMR (176 MHz, CDCl3): δ (ppm) = 167.48, 138.31, 134.52, 131.70, 128.94, 128.74, 128.07, 127.78, 127.09, 44.28. HRMS [C14H13NO+H]+ Expected 212.1081 Observed 212.1068 Melting point: 92-93 °C

Member of collection / collaboration

DOIDescription
10.14469/hpc/14635 Borate-Catalysed Direct Amidation Reactions of Coordinating Substrates. NMR data

Members

DOIDescription
10.14469/hpc/14638 NMR data for compound 3. N-benzylbenzamide. 13C
10.14469/hpc/14637 NMR data for compound 3. N-benzylbenzamide. 1H

Subject Keywords

KeywordValue
Inchi InChI=1S/C14H13NO/c16-14(13-9-5-2-6-10-13)15-11-12-7-3-1-4-8-12/h1-10H,11H2,(H,15,16)
Inchikey LKQUCICFTHBFAL-UHFFFAOYSA-N

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