EPR spectra shown in Figure S4 EPR spectra are baseline-corrected and normalised against the double-integral value for the 'No ROS' sample 12-DSPC treated with superoxide radical treated with hydrogen peroxide treated with hydroxyl radical No ROS + ROS No ROS + ROS No ROS + ROS B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB 330.038 4.38E-07 330.040 6.06E-08 330.038 4.38E-07 330.040 3.67E-07 330.038 4.38E-07 330.040 7.31E-08 330.040 4.35E-07 330.043 5.41E-08 330.040 4.35E-07 330.043 3.63E-07 330.040 4.35E-07 330.043 6.88E-08 330.043 4.31E-07 330.045 4.58E-08 330.043 4.31E-07 330.046 3.58E-07 330.043 4.31E-07 330.046 6.17E-08 330.045 4.22E-07 330.048 3.57E-08 330.045 4.22E-07 330.049 3.53E-07 330.045 4.22E-07 330.049 5.14E-08 330.048 4.08E-07 330.051 2.46E-08 330.048 4.08E-07 330.052 3.46E-07 330.048 4.08E-07 330.052 3.77E-08 330.051 3.89E-07 330.054 1.36E-08 330.051 3.89E-07 330.055 3.39E-07 330.051 3.89E-07 330.055 2.16E-08 330.053 3.64E-07 330.057 3.98E-09 330.053 3.64E-07 330.057 3.31E-07 330.053 3.64E-07 330.058 4.77E-09 330.056 3.33E-07 330.060 -2.88E-09 330.056 3.33E-07 330.060 3.23E-07 330.056 3.33E-07 330.061 -1.07E-08 330.058 2.99E-07 330.063 -6.13E-09 330.058 2.99E-07 330.063 3.15E-07 330.058 2.99E-07 330.063 -2.33E-08 330.061 2.61E-07 330.066 -5.09E-09 330.061 2.61E-07 330.066 3.08E-07 330.061 2.61E-07 330.066 -3.21E-08 330.064 2.21E-07 330.069 6.63E-10 330.064 2.21E-07 330.069 3.01E-07 330.064 2.21E-07 330.069 -3.66E-08 330.066 1.79E-07 330.071 1.12E-08 330.066 1.79E-07 330.072 2.96E-07 330.066 1.79E-07 330.072 -3.71E-08 330.069 1.38E-07 330.074 2.64E-08 330.069 1.38E-07 330.075 2.94E-07 330.069 1.38E-07 330.075 -3.46E-08 330.071 9.75E-08 330.077 4.58E-08 330.071 9.75E-08 330.078 2.94E-07 330.071 9.75E-08 330.078 -3.02E-08 330.074 5.96E-08 330.080 6.85E-08 330.074 5.96E-08 330.081 2.97E-07 330.074 5.96E-08 330.081 -2.56E-08 330.077 2.51E-08 330.083 9.35E-08 330.077 2.51E-08 330.083 3.04E-07 330.077 2.51E-08 330.084 -2.24E-08 330.079 -5.30E-09 330.086 1.20E-07 330.079 -5.30E-09 330.086 3.14E-07 330.079 -5.30E-09 330.087 -2.17E-08 330.082 -3.11E-08 330.089 1.46E-07 330.082 -3.11E-08 330.089 3.26E-07 330.082 -3.11E-08 330.089 -2.46E-08 330.084 -5.21E-08 330.092 1.71E-07 330.084 -5.21E-08 330.092 3.38E-07 330.084 -5.21E-08 330.092 -3.14E-08 330.087 -6.84E-08 330.094 1.94E-07 330.087 -6.84E-08 330.095 3.50E-07 330.087 -6.84E-08 330.095 -4.23E-08 330.090 -8.05E-08 330.097 2.13E-07 330.090 -8.05E-08 330.098 3.59E-07 330.090 -8.05E-08 330.098 -5.65E-08 330.092 -8.86E-08 330.100 2.28E-07 330.092 -8.86E-08 330.101 3.64E-07 330.092 -8.86E-08 330.101 -7.32E-08 330.095 -9.35E-08 330.103 2.38E-07 330.095 -9.35E-08 330.104 3.63E-07 330.095 -9.35E-08 330.104 -9.14E-08 330.097 -9.56E-08 330.106 2.42E-07 330.097 -9.56E-08 330.107 3.56E-07 330.097 -9.56E-08 330.107 -1.10E-07 330.100 -9.54E-08 330.109 2.40E-07 330.100 -9.54E-08 330.109 3.42E-07 330.100 -9.54E-08 330.110 -1.27E-07 330.103 -9.35E-08 330.112 2.32E-07 330.103 -9.35E-08 330.112 3.20E-07 330.103 -9.35E-08 330.112 -1.43E-07 330.105 -9.00E-08 330.114 2.19E-07 330.105 -9.00E-08 330.115 2.93E-07 330.105 -9.00E-08 330.115 -1.56E-07 330.108 -8.54E-08 330.117 2.00E-07 330.108 -8.54E-08 330.118 2.60E-07 330.108 -8.54E-08 330.118 -1.67E-07 330.111 -7.94E-08 330.120 1.76E-07 330.111 -7.94E-08 330.121 2.23E-07 330.111 -7.94E-08 330.121 -1.75E-07 330.113 -7.19E-08 330.123 1.48E-07 330.113 -7.19E-08 330.123 1.85E-07 330.113 -7.19E-08 330.124 -1.80E-07 330.116 -6.24E-08 330.126 1.17E-07 330.116 -6.24E-08 330.126 1.46E-07 330.116 -6.24E-08 330.127 -1.83E-07 330.119 -5.04E-08 330.129 8.53E-08 330.119 -5.04E-08 330.129 1.08E-07 330.119 -5.04E-08 330.129 -1.84E-07 330.121 -3.54E-08 330.131 5.32E-08 330.121 -3.54E-08 330.132 7.35E-08 330.121 -3.54E-08 330.132 -1.82E-07 330.124 -1.68E-08 330.134 2.25E-08 330.124 -1.68E-08 330.135 4.28E-08 330.124 -1.68E-08 330.135 -1.78E-07 330.127 5.39E-09 330.137 -5.19E-09 330.127 5.39E-09 330.138 1.73E-08 330.127 5.39E-09 330.138 -1.71E-07 330.130 3.09E-08 330.140 -2.87E-08 330.130 3.09E-08 330.141 -2.40E-09 330.130 3.09E-08 330.141 -1.62E-07 330.132 5.91E-08 330.143 -4.68E-08 330.132 5.91E-08 330.144 -1.61E-08 330.132 5.91E-08 330.144 -1.51E-07 330.135 8.90E-08 330.146 -5.88E-08 330.135 8.90E-08 330.147 -2.37E-08 330.135 8.90E-08 330.147 -1.38E-07 330.138 1.19E-07 330.149 -6.42E-08 330.138 1.19E-07 330.149 -2.56E-08 330.138 1.19E-07 330.150 -1.22E-07 330.141 1.48E-07 330.152 -6.30E-08 330.141 1.48E-07 330.152 -2.23E-08 330.141 1.48E-07 330.153 -1.06E-07 330.143 1.75E-07 330.155 -5.53E-08 330.143 1.75E-07 330.155 -1.45E-08 330.143 1.75E-07 330.156 -8.90E-08 330.146 1.97E-07 330.158 -4.19E-08 330.146 1.97E-07 330.158 -2.98E-09 330.146 1.97E-07 330.159 -7.19E-08 330.149 2.14E-07 330.161 -2.35E-08 330.149 2.14E-07 330.161 1.12E-08 330.149 2.14E-07 330.162 -5.55E-08 330.152 2.26E-07 330.164 -1.07E-09 330.152 2.26E-07 330.164 2.73E-08 330.152 2.26E-07 330.165 -4.01E-08 330.154 2.31E-07 330.167 2.43E-08 330.154 2.31E-07 330.167 4.44E-08 330.154 2.31E-07 330.167 -2.60E-08 330.157 2.31E-07 330.169 5.17E-08 330.157 2.31E-07 330.170 6.17E-08 330.157 2.31E-07 330.170 -1.28E-08 330.160 2.25E-07 330.172 7.99E-08 330.160 2.25E-07 330.173 7.87E-08 330.160 2.25E-07 330.173 -2.71E-10 330.163 2.15E-07 330.175 1.08E-07 330.163 2.15E-07 330.176 9.50E-08 330.163 2.15E-07 330.176 1.23E-08 330.166 2.03E-07 330.178 1.35E-07 330.166 2.03E-07 330.179 1.10E-07 330.166 2.03E-07 330.179 2.58E-08 330.168 1.90E-07 330.181 1.61E-07 330.168 1.90E-07 330.182 1.24E-07 330.168 1.90E-07 330.182 4.06E-08 330.171 1.77E-07 330.184 1.84E-07 330.171 1.77E-07 330.185 1.36E-07 330.171 1.77E-07 330.185 5.73E-08 330.174 1.66E-07 330.187 2.03E-07 330.174 1.66E-07 330.188 1.47E-07 330.174 1.66E-07 330.188 7.59E-08 330.177 1.58E-07 330.190 2.19E-07 330.177 1.58E-07 330.191 1.56E-07 330.177 1.58E-07 330.191 9.60E-08 330.180 1.53E-07 330.193 2.30E-07 330.180 1.53E-07 330.194 1.62E-07 330.180 1.53E-07 330.194 1.17E-07 330.183 1.53E-07 330.196 2.36E-07 330.183 1.53E-07 330.197 1.65E-07 330.183 1.53E-07 330.197 1.37E-07 330.185 1.57E-07 330.200 2.37E-07 330.185 1.57E-07 330.200 1.64E-07 330.185 1.57E-07 330.201 1.55E-07 330.188 1.66E-07 330.203 2.33E-07 330.188 1.66E-07 330.203 1.59E-07 330.188 1.66E-07 330.204 1.70E-07 330.191 1.79E-07 330.206 2.24E-07 330.191 1.79E-07 330.206 1.48E-07 330.191 1.79E-07 330.207 1.80E-07 330.194 1.97E-07 330.209 2.12E-07 330.194 1.97E-07 330.209 1.31E-07 330.194 1.97E-07 330.210 1.84E-07 330.197 2.17E-07 330.212 1.95E-07 330.197 2.17E-07 330.212 1.07E-07 330.197 2.17E-07 330.213 1.82E-07 330.200 2.39E-07 330.215 1.76E-07 330.200 2.39E-07 330.215 7.79E-08 330.200 2.39E-07 330.216 1.74E-07 330.203 2.62E-07 330.218 1.56E-07 330.203 2.62E-07 330.218 4.28E-08 330.203 2.62E-07 330.219 1.60E-07 330.206 2.84E-07 330.221 1.34E-07 330.206 2.84E-07 330.222 2.91E-09 330.206 2.84E-07 330.222 1.42E-07 330.209 3.05E-07 330.224 1.11E-07 330.209 3.05E-07 330.225 -4.04E-08 330.209 3.05E-07 330.225 1.22E-07 330.211 3.21E-07 330.227 8.91E-08 330.211 3.21E-07 330.228 -8.54E-08 330.211 3.21E-07 330.228 1.01E-07 330.214 3.34E-07 330.230 6.76E-08 330.214 3.34E-07 330.231 -1.31E-07 330.214 3.34E-07 330.231 8.24E-08 330.217 3.41E-07 330.233 4.72E-08 330.217 3.41E-07 330.234 -1.74E-07 330.217 3.41E-07 330.234 6.76E-08 330.220 3.43E-07 330.236 2.79E-08 330.220 3.43E-07 330.237 -2.14E-07 330.220 3.43E-07 330.237 5.82E-08 330.223 3.40E-07 330.239 1.00E-08 330.223 3.40E-07 330.240 -2.49E-07 330.223 3.40E-07 330.240 5.51E-08 330.226 3.31E-07 330.242 -6.49E-09 330.226 3.31E-07 330.243 -2.79E-07 330.226 3.31E-07 330.243 5.86E-08 330.229 3.17E-07 330.245 -2.15E-08 330.229 3.17E-07 330.246 -3.03E-07 330.229 3.17E-07 330.246 6.81E-08 330.232 3.01E-07 330.248 -3.49E-08 330.232 3.01E-07 330.249 -3.20E-07 330.232 3.01E-07 330.249 8.27E-08 330.235 2.82E-07 330.251 -4.67E-08 330.235 2.82E-07 330.252 -3.33E-07 330.235 2.82E-07 330.253 1.01E-07 330.238 2.63E-07 330.255 -5.65E-08 330.238 2.63E-07 330.255 -3.40E-07 330.238 2.63E-07 330.256 1.21E-07 330.241 2.45E-07 330.258 -6.44E-08 330.241 2.45E-07 330.258 -3.44E-07 330.241 2.45E-07 330.259 1.40E-07 330.244 2.28E-07 330.261 -6.99E-08 330.244 2.28E-07 330.262 -3.44E-07 330.244 2.28E-07 330.262 1.58E-07 330.247 2.14E-07 330.264 -7.32E-08 330.247 2.14E-07 330.265 -3.42E-07 330.247 2.14E-07 330.265 1.72E-07 330.250 2.03E-07 330.267 -7.39E-08 330.250 2.03E-07 330.268 -3.38E-07 330.250 2.03E-07 330.268 1.82E-07 330.253 1.96E-07 330.270 -7.22E-08 330.253 1.96E-07 330.271 -3.32E-07 330.253 1.96E-07 330.271 1.86E-07 330.256 1.93E-07 330.273 -6.79E-08 330.256 1.93E-07 330.274 -3.24E-07 330.256 1.93E-07 330.274 1.86E-07 330.259 1.93E-07 330.276 -6.14E-08 330.259 1.93E-07 330.277 -3.15E-07 330.259 1.93E-07 330.277 1.81E-07 330.262 1.95E-07 330.279 -5.28E-08 330.262 1.95E-07 330.280 -3.03E-07 330.262 1.95E-07 330.280 1.72E-07 330.265 2.00E-07 330.282 -4.22E-08 330.265 2.00E-07 330.283 -2.88E-07 330.265 2.00E-07 330.284 1.60E-07 330.268 2.06E-07 330.286 -3.00E-08 330.268 2.06E-07 330.286 -2.70E-07 330.268 2.06E-07 330.287 1.46E-07 330.271 2.13E-07 330.289 -1.65E-08 330.271 2.13E-07 330.289 -2.47E-07 330.271 2.13E-07 330.290 1.31E-07 330.274 2.21E-07 330.292 -1.89E-09 330.274 2.21E-07 330.293 -2.19E-07 330.274 2.21E-07 330.293 1.15E-07 330.277 2.29E-07 330.295 1.36E-08 330.277 2.29E-07 330.296 -1.87E-07 330.277 2.29E-07 330.296 1.01E-07 330.280 2.37E-07 330.298 2.97E-08 330.280 2.37E-07 330.299 -1.49E-07 330.280 2.37E-07 330.299 8.74E-08 330.283 2.46E-07 330.301 4.63E-08 330.283 2.46E-07 330.302 -1.08E-07 330.283 2.46E-07 330.302 7.65E-08 330.286 2.55E-07 330.304 6.32E-08 330.286 2.55E-07 330.305 -6.22E-08 330.286 2.55E-07 330.305 6.86E-08 330.289 2.66E-07 330.307 8.01E-08 330.289 2.66E-07 330.308 -1.44E-08 330.289 2.66E-07 330.308 6.38E-08 330.292 2.78E-07 330.310 9.70E-08 330.292 2.78E-07 330.311 3.43E-08 330.292 2.78E-07 330.311 6.25E-08 330.295 2.93E-07 330.314 1.13E-07 330.295 2.93E-07 330.314 8.25E-08 330.295 2.93E-07 330.315 6.44E-08 330.298 3.11E-07 330.317 1.29E-07 330.298 3.11E-07 330.318 1.28E-07 330.298 3.11E-07 330.318 6.90E-08 330.301 3.32E-07 330.320 1.45E-07 330.301 3.32E-07 330.321 1.70E-07 330.301 3.32E-07 330.321 7.57E-08 330.304 3.55E-07 330.323 1.59E-07 330.304 3.55E-07 330.324 2.06E-07 330.304 3.55E-07 330.324 8.34E-08 330.307 3.80E-07 330.326 1.72E-07 330.307 3.80E-07 330.327 2.36E-07 330.307 3.80E-07 330.327 9.10E-08 330.310 4.05E-07 330.329 1.83E-07 330.310 4.05E-07 330.330 2.57E-07 330.310 4.05E-07 330.330 9.74E-08 330.313 4.30E-07 330.332 1.92E-07 330.313 4.30E-07 330.333 2.71E-07 330.313 4.30E-07 330.333 1.02E-07 330.316 4.53E-07 330.335 1.98E-07 330.316 4.53E-07 330.336 2.76E-07 330.316 4.53E-07 330.336 1.03E-07 330.319 4.72E-07 330.339 2.01E-07 330.319 4.72E-07 330.339 2.74E-07 330.319 4.72E-07 330.340 1.02E-07 330.322 4.86E-07 330.342 2.00E-07 330.322 4.86E-07 330.343 2.65E-07 330.322 4.86E-07 330.343 9.84E-08 330.325 4.94E-07 330.345 1.94E-07 330.325 4.94E-07 330.346 2.52E-07 330.325 4.94E-07 330.346 9.25E-08 330.328 4.95E-07 330.348 1.85E-07 330.328 4.95E-07 330.349 2.36E-07 330.328 4.95E-07 330.349 8.55E-08 330.331 4.88E-07 330.351 1.71E-07 330.331 4.88E-07 330.352 2.19E-07 330.331 4.88E-07 330.352 7.86E-08 330.334 4.75E-07 330.354 1.53E-07 330.334 4.75E-07 330.355 2.04E-07 330.334 4.75E-07 330.355 7.30E-08 330.337 4.54E-07 330.357 1.33E-07 330.337 4.54E-07 330.358 1.92E-07 330.337 4.54E-07 330.358 6.97E-08 330.340 4.27E-07 330.360 1.10E-07 330.340 4.27E-07 330.361 1.85E-07 330.340 4.27E-07 330.362 6.98E-08 330.343 3.96E-07 330.364 8.73E-08 330.343 3.96E-07 330.364 1.83E-07 330.343 3.96E-07 330.365 7.35E-08 330.346 3.60E-07 330.367 6.53E-08 330.346 3.60E-07 330.368 1.86E-07 330.346 3.60E-07 330.368 8.13E-08 330.350 3.22E-07 330.370 4.57E-08 330.350 3.22E-07 330.371 1.95E-07 330.350 3.22E-07 330.371 9.26E-08 330.353 2.82E-07 330.373 2.95E-08 330.353 2.82E-07 330.374 2.07E-07 330.353 2.82E-07 330.374 1.07E-07 330.356 2.42E-07 330.376 1.77E-08 330.356 2.42E-07 330.377 2.22E-07 330.356 2.42E-07 330.377 1.24E-07 330.359 2.02E-07 330.379 1.06E-08 330.359 2.02E-07 330.380 2.37E-07 330.359 2.02E-07 330.380 1.41E-07 330.362 1.64E-07 330.382 8.38E-09 330.362 1.64E-07 330.383 2.50E-07 330.362 1.64E-07 330.383 1.59E-07 330.365 1.28E-07 330.386 1.06E-08 330.365 1.28E-07 330.386 2.60E-07 330.365 1.28E-07 330.387 1.75E-07 330.368 9.44E-08 330.389 1.65E-08 330.368 9.44E-08 330.390 2.64E-07 330.368 9.44E-08 330.390 1.88E-07 330.371 6.40E-08 330.392 2.52E-08 330.371 6.40E-08 330.393 2.61E-07 330.371 6.40E-08 330.393 1.97E-07 330.374 3.71E-08 330.395 3.57E-08 330.374 3.71E-08 330.396 2.50E-07 330.374 3.71E-08 330.396 2.02E-07 330.377 1.37E-08 330.398 4.69E-08 330.377 1.37E-08 330.399 2.31E-07 330.377 1.37E-08 330.399 2.01E-07 330.380 -5.98E-09 330.401 5.79E-08 330.380 -5.98E-09 330.402 2.04E-07 330.380 -5.98E-09 330.402 1.94E-07 330.383 -2.22E-08 330.404 6.80E-08 330.383 -2.22E-08 330.405 1.69E-07 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