EPR spectra shown in Figure S4 EPR spectra are baseline-corrected and normalised against the double-integral value for the 'No ROS' sample 5-DSPC treated with superoxide radical treated with hydrogen peroxide treated with hydroxyl radical No ROS + ROS No ROS + ROS No ROS + ROS B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB 330.036 1.57E-07 330.055 2.19E-07 330.036 1.57E-07 330.055 1.66E-07 330.036 1.57E-07 330.055 1.44E-08 330.039 1.81E-07 330.058 2.24E-07 330.039 1.81E-07 330.058 1.61E-07 330.039 1.81E-07 330.058 2.08E-08 330.041 2.10E-07 330.061 2.32E-07 330.041 2.10E-07 330.061 1.55E-07 330.041 2.10E-07 330.061 2.92E-08 330.044 2.44E-07 330.064 2.41E-07 330.044 2.44E-07 330.064 1.50E-07 330.044 2.44E-07 330.064 3.94E-08 330.047 2.79E-07 330.066 2.51E-07 330.047 2.79E-07 330.067 1.47E-07 330.047 2.79E-07 330.067 5.08E-08 330.049 3.13E-07 330.069 2.63E-07 330.049 3.13E-07 330.070 1.45E-07 330.049 3.13E-07 330.069 6.25E-08 330.052 3.42E-07 330.072 2.76E-07 330.052 3.42E-07 330.073 1.46E-07 330.052 3.42E-07 330.072 7.35E-08 330.055 3.65E-07 330.075 2.88E-07 330.055 3.65E-07 330.076 1.50E-07 330.055 3.65E-07 330.075 8.28E-08 330.057 3.81E-07 330.078 3.01E-07 330.057 3.81E-07 330.079 1.55E-07 330.057 3.81E-07 330.078 8.99E-08 330.060 3.92E-07 330.081 3.13E-07 330.060 3.92E-07 330.081 1.61E-07 330.060 3.92E-07 330.081 9.43E-08 330.063 3.97E-07 330.084 3.23E-07 330.063 3.97E-07 330.084 1.66E-07 330.063 3.97E-07 330.084 9.56E-08 330.065 3.97E-07 330.087 3.32E-07 330.065 3.97E-07 330.087 1.68E-07 330.065 3.97E-07 330.087 9.39E-08 330.068 3.93E-07 330.089 3.39E-07 330.068 3.93E-07 330.090 1.67E-07 330.068 3.93E-07 330.090 8.92E-08 330.071 3.87E-07 330.092 3.43E-07 330.071 3.87E-07 330.093 1.62E-07 330.071 3.87E-07 330.092 8.20E-08 330.073 3.79E-07 330.095 3.43E-07 330.073 3.79E-07 330.096 1.52E-07 330.073 3.79E-07 330.095 7.30E-08 330.076 3.70E-07 330.098 3.40E-07 330.076 3.70E-07 330.099 1.36E-07 330.076 3.70E-07 330.098 6.32E-08 330.079 3.61E-07 330.101 3.33E-07 330.079 3.61E-07 330.102 1.16E-07 330.079 3.61E-07 330.101 5.37E-08 330.081 3.52E-07 330.104 3.23E-07 330.081 3.52E-07 330.105 9.09E-08 330.081 3.52E-07 330.104 4.58E-08 330.084 3.44E-07 330.107 3.11E-07 330.084 3.44E-07 330.107 6.31E-08 330.084 3.44E-07 330.107 4.09E-08 330.087 3.38E-07 330.110 2.96E-07 330.087 3.38E-07 330.110 3.38E-08 330.087 3.38E-07 330.110 4.00E-08 330.089 3.33E-07 330.113 2.80E-07 330.089 3.33E-07 330.113 4.60E-09 330.089 3.33E-07 330.113 4.43E-08 330.092 3.30E-07 330.115 2.64E-07 330.092 3.30E-07 330.116 -2.27E-08 330.092 3.30E-07 330.116 5.44E-08 330.095 3.28E-07 330.118 2.47E-07 330.095 3.28E-07 330.119 -4.68E-08 330.095 3.28E-07 330.118 7.05E-08 330.097 3.28E-07 330.121 2.31E-07 330.097 3.28E-07 330.122 -6.66E-08 330.097 3.28E-07 330.121 9.24E-08 330.100 3.29E-07 330.124 2.14E-07 330.100 3.29E-07 330.125 -8.14E-08 330.100 3.29E-07 330.124 1.20E-07 330.103 3.30E-07 330.127 1.99E-07 330.103 3.30E-07 330.127 -9.11E-08 330.103 3.30E-07 330.127 1.51E-07 330.105 3.33E-07 330.130 1.84E-07 330.105 3.33E-07 330.130 -9.62E-08 330.105 3.33E-07 330.130 1.85E-07 330.108 3.35E-07 330.132 1.69E-07 330.108 3.35E-07 330.133 -9.76E-08 330.108 3.35E-07 330.133 2.20E-07 330.111 3.37E-07 330.135 1.56E-07 330.111 3.37E-07 330.136 -9.65E-08 330.111 3.37E-07 330.135 2.55E-07 330.113 3.39E-07 330.138 1.42E-07 330.113 3.39E-07 330.139 -9.43E-08 330.113 3.39E-07 330.138 2.88E-07 330.116 3.41E-07 330.141 1.30E-07 330.116 3.41E-07 330.142 -9.23E-08 330.116 3.41E-07 330.141 3.16E-07 330.119 3.41E-07 330.144 1.20E-07 330.119 3.41E-07 330.145 -9.18E-08 330.119 3.41E-07 330.144 3.40E-07 330.122 3.39E-07 330.147 1.11E-07 330.122 3.39E-07 330.147 -9.37E-08 330.122 3.39E-07 330.147 3.57E-07 330.124 3.36E-07 330.150 1.05E-07 330.124 3.36E-07 330.150 -9.86E-08 330.124 3.36E-07 330.150 3.67E-07 330.127 3.32E-07 330.152 1.00E-07 330.127 3.32E-07 330.153 -1.07E-07 330.127 3.32E-07 330.153 3.70E-07 330.130 3.26E-07 330.155 9.84E-08 330.130 3.26E-07 330.156 -1.18E-07 330.130 3.26E-07 330.155 3.65E-07 330.133 3.18E-07 330.158 9.79E-08 330.133 3.18E-07 330.159 -1.31E-07 330.133 3.18E-07 330.158 3.52E-07 330.135 3.09E-07 330.161 9.84E-08 330.135 3.09E-07 330.162 -1.46E-07 330.135 3.09E-07 330.161 3.32E-07 330.138 2.99E-07 330.164 9.90E-08 330.138 2.99E-07 330.165 -1.62E-07 330.138 2.99E-07 330.164 3.04E-07 330.141 2.87E-07 330.167 9.87E-08 330.141 2.87E-07 330.168 -1.77E-07 330.141 2.87E-07 330.167 2.72E-07 330.144 2.74E-07 330.170 9.66E-08 330.144 2.74E-07 330.171 -1.90E-07 330.144 2.74E-07 330.170 2.34E-07 330.147 2.60E-07 330.173 9.20E-08 330.147 2.60E-07 330.174 -2.01E-07 330.147 2.60E-07 330.173 1.94E-07 330.149 2.44E-07 330.176 8.45E-08 330.149 2.44E-07 330.177 -2.08E-07 330.149 2.44E-07 330.176 1.54E-07 330.152 2.27E-07 330.179 7.41E-08 330.152 2.27E-07 330.180 -2.11E-07 330.152 2.27E-07 330.179 1.16E-07 330.155 2.08E-07 330.182 6.11E-08 330.155 2.08E-07 330.183 -2.10E-07 330.155 2.08E-07 330.182 8.22E-08 330.158 1.87E-07 330.185 4.63E-08 330.158 1.87E-07 330.186 -2.05E-07 330.158 1.87E-07 330.185 5.53E-08 330.161 1.66E-07 330.188 3.07E-08 330.161 1.66E-07 330.189 -1.96E-07 330.161 1.66E-07 330.188 3.75E-08 330.164 1.44E-07 330.191 1.53E-08 330.164 1.44E-07 330.192 -1.83E-07 330.164 1.44E-07 330.191 3.03E-08 330.166 1.24E-07 330.194 1.06E-09 330.166 1.24E-07 330.194 -1.67E-07 330.166 1.24E-07 330.194 3.44E-08 330.169 1.06E-07 330.197 -1.12E-08 330.169 1.06E-07 330.197 -1.48E-07 330.169 1.06E-07 330.197 4.96E-08 330.172 9.08E-08 330.200 -2.10E-08 330.172 9.08E-08 330.200 -1.27E-07 330.172 9.08E-08 330.200 7.49E-08 330.175 8.10E-08 330.203 -2.83E-08 330.175 8.10E-08 330.204 -1.04E-07 330.175 8.10E-08 330.203 1.08E-07 330.178 7.70E-08 330.206 -3.33E-08 330.178 7.70E-08 330.207 -7.99E-08 330.178 7.70E-08 330.206 1.48E-07 330.181 7.97E-08 330.209 -3.65E-08 330.181 7.97E-08 330.210 -5.43E-08 330.181 7.97E-08 330.209 1.90E-07 330.184 8.93E-08 330.212 -3.85E-08 330.184 8.93E-08 330.213 -2.74E-08 330.184 8.93E-08 330.212 2.32E-07 330.187 1.06E-07 330.215 -4.01E-08 330.187 1.06E-07 330.216 5.29E-10 330.187 1.06E-07 330.215 2.70E-07 330.189 1.28E-07 330.218 -4.18E-08 330.189 1.28E-07 330.219 2.95E-08 330.189 1.28E-07 330.218 3.04E-07 330.192 1.54E-07 330.221 -4.40E-08 330.192 1.54E-07 330.222 5.93E-08 330.192 1.54E-07 330.221 3.31E-07 330.195 1.84E-07 330.224 -4.69E-08 330.195 1.84E-07 330.225 8.96E-08 330.195 1.84E-07 330.224 3.49E-07 330.198 2.15E-07 330.227 -5.04E-08 330.198 2.15E-07 330.228 1.20E-07 330.198 2.15E-07 330.227 3.60E-07 330.201 2.46E-07 330.230 -5.43E-08 330.201 2.46E-07 330.231 1.49E-07 330.201 2.46E-07 330.230 3.62E-07 330.204 2.74E-07 330.233 -5.81E-08 330.204 2.74E-07 330.234 1.78E-07 330.204 2.74E-07 330.233 3.58E-07 330.207 2.98E-07 330.236 -6.15E-08 330.207 2.98E-07 330.237 2.03E-07 330.207 2.98E-07 330.236 3.48E-07 330.210 3.17E-07 330.239 -6.41E-08 330.210 3.17E-07 330.240 2.26E-07 330.210 3.17E-07 330.239 3.33E-07 330.213 3.30E-07 330.242 -6.59E-08 330.213 3.30E-07 330.243 2.45E-07 330.213 3.30E-07 330.242 3.16E-07 330.216 3.37E-07 330.245 -6.69E-08 330.216 3.37E-07 330.246 2.58E-07 330.216 3.37E-07 330.245 2.96E-07 330.219 3.36E-07 330.248 -6.73E-08 330.219 3.36E-07 330.249 2.67E-07 330.219 3.36E-07 330.248 2.76E-07 330.222 3.30E-07 330.251 -6.76E-08 330.222 3.30E-07 330.252 2.71E-07 330.222 3.30E-07 330.251 2.55E-07 330.225 3.17E-07 330.254 -6.79E-08 330.225 3.17E-07 330.255 2.69E-07 330.225 3.17E-07 330.255 2.36E-07 330.228 3.00E-07 330.257 -6.89E-08 330.228 3.00E-07 330.258 2.62E-07 330.228 3.00E-07 330.258 2.18E-07 330.231 2.79E-07 330.261 -7.07E-08 330.231 2.79E-07 330.261 2.51E-07 330.231 2.79E-07 330.261 2.02E-07 330.234 2.55E-07 330.264 -7.34E-08 330.234 2.55E-07 330.265 2.35E-07 330.234 2.55E-07 330.264 1.89E-07 330.237 2.30E-07 330.267 -7.68E-08 330.237 2.30E-07 330.268 2.16E-07 330.237 2.30E-07 330.267 1.78E-07 330.240 2.04E-07 330.270 -8.07E-08 330.240 2.04E-07 330.271 1.94E-07 330.240 2.04E-07 330.270 1.70E-07 330.243 1.79E-07 330.273 -8.44E-08 330.243 1.79E-07 330.274 1.70E-07 330.243 1.79E-07 330.273 1.64E-07 330.246 1.56E-07 330.276 -8.72E-08 330.246 1.56E-07 330.277 1.44E-07 330.246 1.56E-07 330.276 1.61E-07 330.249 1.36E-07 330.279 -8.84E-08 330.249 1.36E-07 330.280 1.16E-07 330.249 1.36E-07 330.279 1.61E-07 330.252 1.19E-07 330.282 -8.74E-08 330.252 1.19E-07 330.283 8.90E-08 330.252 1.19E-07 330.282 1.62E-07 330.255 1.06E-07 330.285 -8.36E-08 330.255 1.06E-07 330.286 6.32E-08 330.255 1.06E-07 330.285 1.66E-07 330.258 9.74E-08 330.288 -7.65E-08 330.258 9.74E-08 330.289 4.03E-08 330.258 9.74E-08 330.289 1.70E-07 330.261 9.43E-08 330.291 -6.62E-08 330.261 9.43E-08 330.292 2.23E-08 330.261 9.43E-08 330.292 1.76E-07 330.264 9.68E-08 330.295 -5.28E-08 330.264 9.68E-08 330.295 1.08E-08 330.264 9.68E-08 330.295 1.82E-07 330.267 1.05E-07 330.298 -3.67E-08 330.267 1.05E-07 330.299 7.57E-09 330.267 1.05E-07 330.298 1.88E-07 330.270 1.19E-07 330.301 -1.83E-08 330.270 1.19E-07 330.302 1.39E-08 330.270 1.19E-07 330.301 1.94E-07 330.273 1.39E-07 330.304 1.69E-09 330.273 1.39E-07 330.305 3.05E-08 330.273 1.39E-07 330.304 1.99E-07 330.276 1.63E-07 330.307 2.26E-08 330.276 1.63E-07 330.308 5.73E-08 330.276 1.63E-07 330.307 2.04E-07 330.279 1.92E-07 330.310 4.39E-08 330.279 1.92E-07 330.311 9.32E-08 330.279 1.92E-07 330.310 2.08E-07 330.282 2.23E-07 330.313 6.50E-08 330.282 2.23E-07 330.314 1.36E-07 330.282 2.23E-07 330.313 2.11E-07 330.285 2.56E-07 330.316 8.54E-08 330.285 2.56E-07 330.317 1.84E-07 330.285 2.56E-07 330.316 2.14E-07 330.288 2.88E-07 330.319 1.05E-07 330.288 2.88E-07 330.320 2.34E-07 330.288 2.88E-07 330.320 2.16E-07 330.291 3.17E-07 330.322 1.23E-07 330.291 3.17E-07 330.323 2.82E-07 330.291 3.17E-07 330.323 2.17E-07 330.294 3.42E-07 330.326 1.39E-07 330.294 3.42E-07 330.327 3.26E-07 330.294 3.42E-07 330.326 2.17E-07 330.297 3.59E-07 330.329 1.53E-07 330.297 3.59E-07 330.330 3.61E-07 330.297 3.59E-07 330.329 2.16E-07 330.300 3.69E-07 330.332 1.66E-07 330.300 3.69E-07 330.333 3.88E-07 330.300 3.69E-07 330.332 2.14E-07 330.303 3.69E-07 330.335 1.76E-07 330.303 3.69E-07 330.336 4.04E-07 330.303 3.69E-07 330.335 2.11E-07 330.306 3.59E-07 330.338 1.84E-07 330.306 3.59E-07 330.339 4.08E-07 330.306 3.59E-07 330.338 2.07E-07 330.309 3.40E-07 330.341 1.90E-07 330.309 3.40E-07 330.342 4.03E-07 330.309 3.40E-07 330.341 2.02E-07 330.312 3.11E-07 330.344 1.93E-07 330.312 3.11E-07 330.345 3.89E-07 330.312 3.11E-07 330.345 1.98E-07 330.316 2.75E-07 330.347 1.93E-07 330.316 2.75E-07 330.348 3.69E-07 330.316 2.75E-07 330.348 1.95E-07 330.319 2.32E-07 330.351 1.90E-07 330.319 2.32E-07 330.352 3.43E-07 330.319 2.32E-07 330.351 1.93E-07 330.322 1.85E-07 330.354 1.84E-07 330.322 1.85E-07 330.355 3.14E-07 330.322 1.85E-07 330.354 1.95E-07 330.325 1.37E-07 330.357 1.74E-07 330.325 1.37E-07 330.358 2.85E-07 330.325 1.37E-07 330.357 1.99E-07 330.328 8.99E-08 330.360 1.61E-07 330.328 8.99E-08 330.361 2.55E-07 330.328 8.99E-08 330.360 2.08E-07 330.331 4.57E-08 330.363 1.45E-07 330.331 4.57E-08 330.364 2.26E-07 330.331 4.57E-08 330.363 2.20E-07 330.334 6.43E-09 330.366 1.25E-07 330.334 6.43E-09 330.367 1.99E-07 330.334 6.43E-09 330.366 2.36E-07 330.337 -2.63E-08 330.369 1.02E-07 330.337 -2.63E-08 330.370 1.73E-07 330.337 -2.63E-08 330.370 2.55E-07 330.340 -5.17E-08 330.373 7.72E-08 330.340 -5.17E-08 330.373 1.48E-07 330.340 -5.17E-08 330.373 2.76E-07 330.343 -6.93E-08 330.376 5.07E-08 330.343 -6.93E-08 330.377 1.24E-07 330.343 -6.93E-08 330.376 2.98E-07 330.346 -7.97E-08 330.379 2.39E-08 330.346 -7.97E-08 330.380 1.01E-07 330.346 -7.97E-08 330.379 3.19E-07 330.350 -8.36E-08 330.382 -2.03E-09 330.350 -8.36E-08 330.383 7.88E-08 330.350 -8.36E-08 330.382 3.38E-07 330.353 -8.22E-08 330.385 -2.57E-08 330.353 -8.22E-08 330.386 5.74E-08 330.353 -8.22E-08 330.385 3.52E-07 330.356 -7.71E-08 330.388 -4.57E-08 330.356 -7.71E-08 330.389 3.71E-08 330.356 -7.71E-08 330.388 3.60E-07 330.359 -6.99E-08 330.391 -6.08E-08 330.359 -6.99E-08 330.392 1.81E-08 330.359 -6.99E-08 330.392 3.62E-07 330.362 -6.22E-08 330.394 -7.00E-08 330.362 -6.22E-08 330.395 7.49E-10 330.362 -6.22E-08 330.395 3.54E-07 330.365 -5.52E-08 330.398 -7.26E-08 330.365 -5.52E-08 330.398 -1.49E-08 330.365 -5.52E-08 330.398 3.38E-07 330.368 -5.01E-08 330.401 -6.80E-08 330.368 -5.01E-08 330.402 -2.87E-08 330.368 -5.01E-08 330.401 3.13E-07 330.371 -4.74E-08 330.404 -5.66E-08 330.371 -4.74E-08 330.405 -4.09E-08 330.371 -4.74E-08 330.404 2.80E-07 330.374 -4.76E-08 330.407 -3.87E-08 330.374 -4.76E-08 330.408 -5.16E-08 330.374 -4.76E-08 330.407 2.40E-07 330.377 -5.06E-08 330.410 -1.54E-08 330.377 -5.06E-08 330.411 -6.12E-08 330.377 -5.06E-08 330.410 1.95E-07 330.381 -5.61E-08 330.413 1.20E-08 330.381 -5.61E-08 330.414 -7.01E-08 330.381 -5.61E-08 330.414 1.47E-07 330.384 -6.39E-08 330.416 4.19E-08 330.384 -6.39E-08 330.417 -7.85E-08 330.384 -6.39E-08 330.417 9.89E-08 330.387 -7.33E-08 330.420 7.28E-08 330.387 -7.33E-08 330.420 -8.66E-08 330.387 -7.33E-08 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