EPR spectra shown in Figure S4 EPR spectra are baseline-corrected and normalised against the double-integral value for the 'No ROS' sample 5-DSPC treated with hydrogen peroxide treated with hydroxyl radical No ROS Low High No ROS Low High B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB B in mT dchi''/dB 331.0615848 -2.74E-08 331.0890854 -2.04E-08 331.0844521 5.68E-08 331.0615848 -2.74E-08 331.0794255 1.55E-07 331.0875923 -6.99E-08 331.0642764 -2.61E-08 331.0919782 -1.00E-08 331.0873394 4.38E-08 331.0642764 -2.61E-08 331.0823178 1.32E-07 331.0904761 -7.31E-08 331.0669679 -2.38E-08 331.094871 3.33E-09 331.0902266 2.86E-08 331.0669679 -2.38E-08 331.0852101 1.09E-07 331.0933599 -7.38E-08 331.0696594 -2.11E-08 331.0977638 1.92E-08 331.0931138 1.23E-08 331.0696594 -2.11E-08 331.0881024 8.69E-08 331.0962436 -7.20E-08 331.072351 -1.82E-08 331.1006566 3.82E-08 331.096001 -4.59E-09 331.072351 -1.82E-08 331.0909946 6.69E-08 331.0991274 -6.66E-08 331.0750425 -1.52E-08 331.1035494 6.06E-08 331.0988882 -2.11E-08 331.0750425 -1.52E-08 331.0938869 4.98E-08 331.1020112 -5.70E-08 331.077734 -1.22E-08 331.1064422 8.52E-08 331.1017754 -3.68E-08 331.077734 -1.22E-08 331.0967792 3.48E-08 331.104895 -4.39E-08 331.0804256 -9.90E-09 331.109335 1.11E-07 331.1046626 -5.08E-08 331.0804256 -9.90E-09 331.0996715 2.24E-08 331.1077788 -2.78E-08 331.0831171 -8.48E-09 331.1122278 1.38E-07 331.1075499 -6.30E-08 331.0831171 -8.48E-09 331.1025637 1.27E-08 331.1106625 -8.78E-09 331.0858087 -7.79E-09 331.1151207 1.64E-07 331.1104371 -7.30E-08 331.0858087 -7.79E-09 331.105456 4.69E-09 331.1135463 1.21E-08 331.0885002 -8.27E-09 331.1180135 1.87E-07 331.1133243 -8.11E-08 331.0885002 -8.27E-09 331.1083483 -2.31E-09 331.1164301 3.34E-08 331.0911917 -1.00E-08 331.1209063 2.07E-07 331.1162115 -8.73E-08 331.0911917 -1.00E-08 331.1112406 -8.36E-09 331.1193139 5.44E-08 331.0938833 -1.28E-08 331.1237991 2.24E-07 331.1190987 -9.20E-08 331.0938833 -1.28E-08 331.1141328 -1.37E-08 331.1221977 7.45E-08 331.0965748 -1.61E-08 331.1266919 2.35E-07 331.1219859 -9.56E-08 331.0965748 -1.61E-08 331.1170251 -1.93E-08 331.1250814 9.22E-08 331.0992664 -2.00E-08 331.1295847 2.40E-07 331.1248732 -9.81E-08 331.0992664 -2.00E-08 331.1199174 -2.54E-08 331.1279652 1.07E-07 331.1019579 -2.43E-08 331.1324775 2.41E-07 331.1277604 -9.97E-08 331.1019579 -2.43E-08 331.1228097 -3.16E-08 331.130849 1.19E-07 331.1046494 -2.84E-08 331.1353703 2.38E-07 331.1306476 -1.00E-07 331.1046494 -2.84E-08 331.1257019 -3.78E-08 331.1337328 1.27E-07 331.107341 -3.19E-08 331.1382632 2.29E-07 331.1335348 -9.94E-08 331.107341 -3.19E-08 331.1285942 -4.45E-08 331.1366166 1.33E-07 331.1100325 -3.49E-08 331.141156 2.18E-07 331.136422 -9.70E-08 331.1100325 -3.49E-08 331.1314865 -5.08E-08 331.1395003 1.35E-07 331.1127241 -3.72E-08 331.1440488 2.04E-07 331.1393092 -9.24E-08 331.1127241 -3.72E-08 331.1343788 -5.58E-08 331.1423841 1.36E-07 331.1153562 -3.86E-08 331.1469416 1.89E-07 331.1421964 -8.55E-08 331.1153562 -3.86E-08 331.137271 -5.98E-08 331.1452679 1.35E-07 331.117975 -3.95E-08 331.1498344 1.72E-07 331.1450837 -7.59E-08 331.117975 -3.95E-08 331.1401633 -6.22E-08 331.1481517 1.32E-07 331.120617 -4.01E-08 331.1527272 1.55E-07 331.1479709 -6.38E-08 331.120617 -4.01E-08 331.1430556 -6.24E-08 331.1510355 1.28E-07 331.1232763 -4.08E-08 331.15562 1.40E-07 331.1508581 -4.92E-08 331.1232763 -4.08E-08 331.1459479 -6.05E-08 331.1539192 1.25E-07 331.1259481 -4.17E-08 331.1584313 1.24E-07 331.1536704 -3.26E-08 331.1259481 -4.17E-08 331.1487628 -5.70E-08 331.1567237 1.20E-07 331.1286314 -4.39E-08 331.1612163 1.10E-07 331.1564587 -1.47E-08 331.1286314 -4.39E-08 331.1515544 -5.19E-08 331.1595026 1.15E-07 331.1313265 -4.73E-08 331.164023 9.77E-08 331.1592651 3.90E-09 331.1313265 -4.73E-08 331.154367 -4.55E-08 331.1623012 1.10E-07 331.1340347 -5.20E-08 331.1668465 8.69E-08 331.1620861 2.22E-08 331.1340347 -5.20E-08 331.1571972 -3.86E-08 331.1651164 1.04E-07 331.1367574 -5.83E-08 331.1696833 7.76E-08 331.1649195 3.96E-08 331.1367574 -5.83E-08 331.1600455 -3.23E-08 331.1679479 9.72E-08 331.1394889 -6.59E-08 331.1725326 7.01E-08 331.1677651 5.54E-08 331.1394889 -6.59E-08 331.162909 -2.66E-08 331.1707945 8.92E-08 331.1422265 -7.48E-08 331.1753922 6.48E-08 331.1706205 6.92E-08 331.1422265 -7.48E-08 331.1657799 -2.21E-08 331.1736522 8.01E-08 331.1449714 -8.45E-08 331.1782614 6.07E-08 331.1734859 8.08E-08 331.1449714 -8.45E-08 331.1686554 -2.00E-08 331.1765202 6.94E-08 331.1477252 -9.49E-08 331.1811393 5.79E-08 331.1763638 9.00E-08 331.1477252 -9.49E-08 331.1715373 -1.99E-08 331.1793975 5.70E-08 331.1504892 -1.06E-07 331.1840251 5.68E-08 331.1792503 9.70E-08 331.1504892 -1.06E-07 331.1744271 -2.19E-08 331.1822813 4.39E-08 331.1532654 -1.17E-07 331.1869216 5.68E-08 331.182145 1.02E-07 331.1532654 -1.17E-07 331.1773267 -2.62E-08 331.185172 2.99E-08 331.1560515 -1.29E-07 331.1898309 5.67E-08 331.1850503 1.05E-07 331.1560515 -1.29E-07 331.1802347 -3.27E-08 331.1880709 1.48E-08 331.1588413 -1.41E-07 331.1927501 5.69E-08 331.1879635 1.07E-07 331.1588413 -1.41E-07 331.1831472 -4.06E-08 331.1909777 -3.36E-10 331.1616336 -1.54E-07 331.1956762 5.77E-08 331.1908838 1.07E-07 331.1616336 -1.54E-07 331.1860658 -4.95E-08 331.1938918 -1.50E-08 331.1644306 -1.67E-07 331.1986103 5.78E-08 331.1938118 1.06E-07 331.1644306 -1.67E-07 331.1889926 -5.97E-08 331.1968125 -2.97E-08 331.1672327 -1.80E-07 331.2015561 5.70E-08 331.1967505 1.04E-07 331.1672327 -1.80E-07 331.1919271 -7.03E-08 331.1997404 -4.41E-08 331.170041 -1.93E-07 331.2045094 5.61E-08 331.1996966 1.01E-07 331.170041 -1.93E-07 331.1948684 -8.08E-08 331.2026786 -5.75E-08 331.17286 -2.06E-07 331.2074663 5.46E-08 331.2026442 9.66E-08 331.17286 -2.06E-07 331.19782 -9.12E-08 331.2056287 -7.01E-08 331.1756902 -2.18E-07 331.2104269 5.21E-08 331.2055949 9.09E-08 331.1756902 -2.18E-07 331.2007852 -1.02E-07 331.2085883 -8.23E-08 331.178528 -2.29E-07 331.2133946 4.91E-08 331.2085532 8.38E-08 331.178528 -2.29E-07 331.2037582 -1.12E-07 331.2115536 -9.39E-08 331.1813727 -2.37E-07 331.2163692 4.60E-08 331.2115197 7.53E-08 331.1813727 -2.37E-07 331.2067351 -1.22E-07 331.2145237 -1.05E-07 331.1842245 -2.42E-07 331.2193481 4.21E-08 331.214494 6.53E-08 331.1842245 -2.42E-07 331.2097152 -1.32E-07 331.2174992 -1.15E-07 331.1870811 -2.44E-07 331.2223319 3.75E-08 331.2174765 5.46E-08 331.1870811 -2.44E-07 331.212699 -1.42E-07 331.2204799 -1.25E-07 331.189943 -2.42E-07 331.2253225 3.30E-08 331.2204654 4.36E-08 331.189943 -2.42E-07 331.2156892 -1.51E-07 331.2234659 -1.35E-07 331.192812 -2.35E-07 331.2283217 2.86E-08 331.2234579 3.27E-08 331.192812 -2.35E-07 331.2186879 -1.59E-07 331.2264579 -1.43E-07 331.1956873 -2.25E-07 331.23133 2.36E-08 331.2264558 2.28E-08 331.1956873 -2.25E-07 331.221693 -1.67E-07 331.2294565 -1.50E-07 331.1985683 -2.11E-07 331.2343424 1.86E-08 331.2294597 1.46E-08 331.1985683 -2.11E-07 331.2247003 -1.73E-07 331.2324627 -1.55E-07 331.2014571 -1.94E-07 331.2373575 1.45E-08 331.2324669 8.74E-09 331.2014571 -1.94E-07 331.2277129 -1.75E-07 331.2354782 -1.58E-07 331.2043551 -1.75E-07 331.240378 1.05E-08 331.2354776 5.38E-09 331.2043551 -1.75E-07 331.2307343 -1.75E-07 331.2384988 -1.58E-07 331.2072616 -1.55E-07 331.2434041 6.93E-09 331.2384947 5.09E-09 331.2072616 -1.55E-07 331.233761 -1.72E-07 331.2415204 -1.56E-07 331.2101739 -1.33E-07 331.2464341 4.62E-09 331.2415188 7.39E-09 331.2101739 -1.33E-07 331.2367931 -1.65E-07 331.244545 -1.51E-07 331.2130889 -1.11E-07 331.2494668 3.87E-09 331.2445486 1.20E-08 331.2130889 -1.11E-07 331.2398298 -1.54E-07 331.2475754 -1.43E-07 331.2160078 -8.88E-08 331.2525021 4.10E-09 331.2475827 1.82E-08 331.2160078 -8.88E-08 331.2428672 -1.42E-07 331.2506113 -1.33E-07 331.2189313 -6.67E-08 331.2555409 5.97E-09 331.2506204 2.49E-08 331.2189313 -6.67E-08 331.2459041 -1.28E-07 331.2536518 -1.22E-07 331.2218603 -4.46E-08 331.2585841 1.02E-08 331.2536609 3.14E-08 331.2218603 -4.46E-08 331.2489422 -1.13E-07 331.2566951 -1.09E-07 331.2247938 -2.25E-08 331.2616334 1.57E-08 331.2567073 3.63E-08 331.2247938 -2.25E-08 331.2519847 -9.84E-08 331.25974 -9.60E-08 331.2277324 -1.29E-10 331.2646864 2.24E-08 331.2597582 3.93E-08 331.2277324 -1.29E-10 331.2550329 -8.58E-08 331.2627867 -8.40E-08 331.2306783 2.27E-08 331.2677423 3.05E-08 331.2628108 3.95E-08 331.2306783 2.27E-08 331.2580855 -7.52E-08 331.2658358 -7.27E-08 331.2336302 4.60E-08 331.2708028 3.96E-08 331.2658642 3.71E-08 331.2336302 4.60E-08 331.2611436 -6.72E-08 331.2688889 -6.26E-08 331.2365864 6.97E-08 331.2738667 4.84E-08 331.2689198 3.20E-08 331.2365864 6.97E-08 331.2642076 -6.28E-08 331.2719446 -5.43E-08 331.2395475 9.36E-08 331.2769332 5.65E-08 331.2719807 2.48E-08 331.2395475 9.36E-08 331.2672759 -6.10E-08 331.275004 -4.75E-08 331.2425127 1.17E-07 331.280003 6.42E-08 331.2750494 1.66E-08 331.2425127 1.17E-07 331.2703457 -6.13E-08 331.2780688 -4.17E-08 331.2454806 1.41E-07 331.2830742 7.03E-08 331.2781208 8.30E-09 331.2454806 1.41E-07 331.2734143 -6.36E-08 331.2811374 -3.69E-08 331.2484527 1.63E-07 331.2861456 7.41E-08 331.2811911 9.16E-10 331.2484527 1.63E-07 331.2764818 -6.68E-08 331.284208 -3.35E-08 331.251429 1.83E-07 331.2892198 7.60E-08 331.2842625 -4.80E-09 331.251429 1.83E-07 331.2795518 -6.99E-08 331.2872816 -3.04E-08 331.2544078 2.02E-07 331.2922991 7.62E-08 331.2873385 -7.90E-09 331.2544078 2.02E-07 331.2826291 -7.26E-08 331.2903587 -2.75E-08 331.2573933 2.19E-07 331.2953812 7.38E-08 331.2904177 -8.06E-09 331.2573933 2.19E-07 331.2857124 -7.50E-08 331.293439 -2.58E-08 331.2603891 2.33E-07 331.2984658 6.95E-08 331.2934991 -5.20E-09 331.2603891 2.33E-07 331.2887987 -7.63E-08 331.2965222 -2.50E-08 331.2633896 2.45E-07 331.3015554 6.39E-08 331.2965832 6.66E-10 331.2633896 2.45E-07 331.2918858 -7.64E-08 331.2996067 -2.47E-08 331.2663934 2.54E-07 331.3046489 5.70E-08 331.2996691 8.78E-09 331.2663934 2.54E-07 331.2949741 -7.61E-08 331.3026917 -2.54E-08 331.2694055 2.62E-07 331.3077441 4.88E-08 331.302757 1.86E-08 331.2694055 2.62E-07 331.2980634 -7.58E-08 331.3057766 -2.75E-08 331.2724252 2.69E-07 331.3108409 4.02E-08 331.3058496 2.91E-08 331.2724252 2.69E-07 331.3011545 -7.53E-08 331.3088638 -3.03E-08 331.275449 2.74E-07 331.313941 3.19E-08 331.3089454 3.96E-08 331.275449 2.74E-07 331.3042486 -7.49E-08 331.3119581 -3.35E-08 331.2784768 2.78E-07 331.317044 2.32E-08 331.3120397 4.86E-08 331.2784768 2.78E-07 331.3073464 -7.52E-08 331.315057 -3.76E-08 331.2815082 2.80E-07 331.320149 1.45E-08 331.3151336 5.56E-08 331.2815082 2.80E-07 331.3104474 -7.57E-08 331.3181543 -4.20E-08 331.2845402 2.82E-07 331.3232534 7.08E-09 331.3182296 5.98E-08 331.2845402 2.82E-07 331.3135498 -7.59E-08 331.3212494 -4.59E-08 331.287573 2.82E-07 331.3263562 4.63E-10 331.3213279 6.09E-08 331.287573 2.82E-07 331.3166526 -7.60E-08 331.3243476 -4.92E-08 331.2906107 2.80E-07 331.3294593 -5.61E-09 331.3244287 5.86E-08 331.2906107 2.80E-07 331.3197546 -7.55E-08 331.3274506 -5.24E-08 331.2936561 2.76E-07 331.3325663 -1.06E-08 331.3275305 5.33E-08 331.2936561 2.76E-07 331.3228556 -7.34E-08 331.3305582 -5.46E-08 331.2967048 2.68E-07 331.3356776 -1.38E-08 331.3306321 4.52E-08 331.2967048 2.68E-07 331.3259587 -6.93E-08 331.3336683 -5.59E-08 331.2997549 2.57E-07 331.3387921 -1.61E-08 331.3337355 3.48E-08 331.2997549 2.57E-07 331.3290659 -6.35E-08 331.3367805 -5.70E-08 331.3028092 2.41E-07 331.3419096 -1.73E-08 331.3368434 2.28E-08 331.3028092 2.41E-07 331.3321773 -5.54E-08 331.3398959 -5.79E-08 331.3058668 2.22E-07 331.3450308 -1.69E-08 331.3399563 9.71E-09 331.3058668 2.22E-07 331.335291 -4.49E-08 331.3430124 -5.84E-08 331.3089246 1.98E-07 331.3481531 -1.52E-08 331.3430717 -3.86E-09 331.3089246 1.98E-07 331.3384048 -3.25E-08 331.3461274 -5.88E-08 331.3119837 1.70E-07 331.3512739 -1.31E-08 331.3461869 -1.73E-08 331.3119837 1.70E-07 331.3415193 -1.94E-08 331.3492397 -5.95E-08 331.3150454 1.38E-07 331.3543947 -1.03E-08 331.3493026 -3.05E-08 331.3150454 1.38E-07 331.3446377 -5.52E-09 331.3523504 -5.99E-08 331.3181085 1.05E-07 331.3575164 -6.69E-09 331.3524197 -4.30E-08 331.3181085 1.05E-07 331.3477596 8.11E-09 331.3554621 -5.99E-08 331.3211751 6.99E-08 331.3606386 -3.80E-09 331.3555362 -5.53E-08 331.3211751 6.99E-08 331.3508833 2.01E-08 331.3585759 -5.95E-08 331.324249 3.42E-08 331.3637632 -1.78E-09 331.3586514 -6.70E-08 331.324249 3.42E-08 331.3540082 2.98E-08 331.361695 -5.86E-08 331.3273309 -7.74E-10 331.3668897 -4.24E-10 331.3617671 -7.84E-08 331.3273309 -7.74E-10 331.3571327 3.71E-08 331.3648194 -5.66E-08 331.3304148 -3.40E-08 331.3700135 -3.23E-10 331.3648831 -8.95E-08 331.3304148 -3.40E-08 331.3602572 4.12E-08 331.3679452 -5.32E-08 331.3334962 -6.50E-08 331.3731323 -2.42E-09 331.3680001 -1.00E-07 331.3334962 -6.50E-08 331.3633851 4.19E-08 331.3710708 -4.93E-08 331.3365795 -9.30E-08 331.3762514 -6.17E-09 331.3711215 -1.11E-07 331.3365795 -9.30E-08 331.3665164 3.98E-08 331.3741966 -4.43E-08 331.3396689 -1.17E-07 331.3793739 -1.08E-08 331.374248 -1.20E-07 331.3396689 -1.17E-07 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