Syntheses and Characterization of Main Group, Transition Metal, Lanthanide and Actinide Complexes of Bidentate Acylpyrazolone Ligands
DOI: 10.14469/hpc/10386 Metadata
Created: 2022-04-22 11:34
Last modified: 2024-11-14 09:26
License: Creative Commons: Public Domain Dedication 1.0
Funding: (none given)
Co-author: Henry Rzepa Co-author: Andrew White Co-author: Anthony Barrett Co-author: Luciano Barluzzi Co-author: Richard Layfield
Description
The synthesis of acylpyrazolone salts and their complexes of main group elements, transition metals, lanthanides, and actinides are described and characterized inter alia by means of single-crystal X-ray crystallography, NMR, and IR spectroscopies. The complexes consist of two, three, or four acylprazolone ligands bound to the metal atom, resulting in a structurally diverse set of coordination complexes with (distorted) octahedral, pentagonal-bipyramidal, or antiprismatic arrangements. Several complexes proved to be polymeric in the solid state including heterobimetallic sodium/lanthanide coordination polymers. A selection of the polymeric compounds was analyzed via TG/DTA measurements to establish their stability. The ligands, in turn, were readily synthesized in good yields from commercially available hydrazine hydrochloride salts. These findings demonstrate that acylpyrazolone ligands can form complexes with metals of varying ionic radii, highlighted by their utility in other areas such as analytical and metal organic framework chemistry.
Members
| DOI | Description |
|---|---|
| 10.14469/hpc/14300 | IUPAC FAIRSpec Collection with associated IUPAC FAIRSpec Finding Aid and Subject Metadata/Media Type vocabulary |
| 10.14469/hpc/11748 | Compound 74: Bis(4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-olate)dioxouranium |
| 10.14469/hpc/11349 | Compound 21: Bis(ethanol) bis(4-benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-olate)calcium |
| 10.14469/hpc/11405 | Compound 60: Bis(ethanol) bis((4-(ethoxycarbonyl)-1H-pyrazol-5-yl)oxy)nickel |
| 10.14469/hpc/11406 | Compound 61: Sodium(I) tetrakis((4-(ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)lanthanum |
| 10.14469/hpc/11347 | Compound 20: bis(4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-olate) calcium |
| 10.14469/hpc/11404 | Compound 58: bis((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy) |
| 10.14469/hpc/11395 | Compound 40: Bis(ethyl 5-hydroxy-1-phenyl-1H-pyrazole-4-carboxylate)tetrakis(acetato)dirhodium |
| 10.14469/hpc/11343 | Compound 19: bis(4-(ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-olate)calcium |
| 10.14469/hpc/11709 | Compound 8: Ethyl 2-(4-Methoxybenzyl)-3-oxo-2,3-dihydro-1H-pyrazole-4-carboxylate |
| 10.14469/hpc/11376 | Compound 39: Bis(ethyl 5-hydroxy-1-(4-methoxybenzyl)-1H-pyrazole-4-carboxylate)tetrakis(acetato)dirhodium |
| 10.14469/hpc/11339 | Compound 18: Bis(ethanol) bis(4-(ethoxycarbonyl)-1H-pyrazol-5-olate)magnesium |
| 10.14469/hpc/11799 | Compound 5: Ethyl 3-oxo-2,3-dihydro-1H-pyrazole-4-carboxylate |
| 10.14469/hpc/11711 | Compound 10: 4-Benzoyl-2-(4-methoxybenzyl)-1,2-dihydro-3H-pyrazol-3-one |
| 10.14469/hpc/10385 | Compound 56: bis((4-(ethoxycarbonyl)-1H-pyrazol-5-yl)oxy)copper |
| 10.14469/hpc/11337 | Compound 17: Bis(ethanol) bis(4-benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-olate)magnesium |
| 10.14469/hpc/11710 | Compound 9: 2-(4-Methoxybenzyl)-2,4-dihydro-3H-pyrazol-3-one |
| 10.14469/hpc/11402 | Compound 55: bis((4-benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)copper |
| 10.14469/hpc/11375 | Compound 38: (m-O)-Di-[cyclopentadienyl-bis((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy)zirconium] |
| 10.14469/hpc/11335 | Compound 16: bis(4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-olate)magnesium |
| 10.14469/hpc/11747 | Compound 73: Bis(4-(ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-olate)dioxouranium |
| 10.14469/hpc/11401 | Compound 54: Bis((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy)copper polymer |
| 10.14469/hpc/11374 | Compound 37: Cyclopentadienyl-bis((4-(ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)zirconium chloride |
| 10.14469/hpc/11400 | Compound 53: Bis(ethanol) bis((4-(ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)copper |
| 10.14469/hpc/11373 | Compound 34: Tetrakis((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy)zirconium |
| 10.14469/hpc/11749 | Compound 75: Bis(4-benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-olate)dioxouranium |
| 10.14469/hpc/11399 | Compound 50: Bis(ethanol) bis((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy)zinc |
| 10.14469/hpc/11372 | Compound 33: Tetrakis((4-(ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)zirconium |
| 10.14469/hpc/11329 | Compound 14: (4-(Ethoxycarbonyl)-1H-pyrazol-5-olate)sodium |
| 10.14469/hpc/11410 | Compound 70: Tris((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy)ytterbium |
| 10.14469/hpc/11403 | Compound 57: Bis((4-(ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)nickel |
| 10.14469/hpc/11407 | Compound 62: tris((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy)lanthanum |
| 10.14469/hpc/11358 | Compound 24: Tris((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy)scandium |
| 10.14469/hpc/11396 | Compound 42: bis((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy)manganese |
| 10.14469/hpc/11408 | Compound 65: Sodium(I) tetrakis((4-(ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)dysprosium |
| 10.14469/hpc/11298 | Compound 11: (4-(Ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-olate)sodium |
| 10.14469/hpc/11360 | Compound 25: Tris((4-benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)scandium ethanol dimer |
| 10.14469/hpc/11397 | Compound 46: Tris((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy)iron |
| 10.14469/hpc/11409 | Compound 66: Tris((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy)dysprosium |
| 10.14469/hpc/11257 | Compound 12: (4-(Ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-olate)sodium |
| 10.14469/hpc/11362 | Compound 28: Tris((4-(ethoxycarbonyl)-1-phenyl-1H-pyrazol-5-yl)oxy)yttrium |
| 10.14469/hpc/11398 | Compound 49: ((4-(Ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)zinc polymer |
| 10.14469/hpc/11708 | Compound 6: Ethyl 3-Oxo-2-phenyl-2,3-dihydro-1H-pyrazole-4-carboxylate |
| 10.14469/hpc/12307 | Compound 76: Bis((4-(ethoxycarbonyl)-1H-pyrazol-5-yl)oxy)dioxouranium |
| 10.14469/hpc/11331 | Compound 15: bis(4-(ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-olate)magnesium |
| 10.14469/hpc/11726 | Compound 44. Bis(ethanol) bis((4-(ethoxycarbonyl)-1H-pyrazol-5-yl)oxy)manganese |
| 10.14469/hpc/11745 | Compound 69: Tris((4-(ethoxycarbonyl)-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)ytterbium |
| 10.14469/hpc/11744 | Compound 68: Tris((4-(ethoxycarbonyl)-1H-pyrazol-5-yl)oxy)dysprosium (68) |
| 10.14469/hpc/11743 | Compound 67: Tris((4-benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)dysprosium |
| 10.14469/hpc/11712 | Compound 13: (4-Benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-olate)sodium |
| 10.14469/hpc/11740 | Compound 59: Bis(ethanol) bis((4-benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)nickel |
| 10.14469/hpc/11746 | Compound 71: Tris((4-benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)ytterbium |
| 10.14469/hpc/11742 | Compound 64: Tris((4-(ethoxycarbonyl)-1H-pyrazol-5-yl)oxy)lanthanum |
| 10.14469/hpc/11741 | Compound 63: Tris((4-benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)lanthanum |
| 10.14469/hpc/11733 | Compound 52: Bis(ethanol) bis((4-(ethoxycarbonyl)-1H-pyrazol-5-yl)oxy)zinc |
| 10.14469/hpc/11714 | Compound 26: Tris((4-(ethoxycarbonyl)-1H-pyrazol-5-yl)oxy)scandium |
| 10.14469/hpc/14707 | Compound 43: bis((4-benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)manganese |
| 10.14469/hpc/11732 | Compound 51: ((4-Benzoyl-1-(4-methoxybenzyl)-1H-pyrazol-5-yl)oxy)zinc polymer |
Associated DOIs
| Current dataset ... | DOI | Description |
|---|---|---|
| References | 10.1021/acs.inorgchem.3c01506 | 10.1021/acs.inorgchem.3c01506 |
| isReferencedBy | 10.1021/acs.inorgchem.3c01506 | 10.1021/acs.inorgchem.3c01506 |