Copper Catalysed Oxidative alpha-Sulfonylation of Branched Aldehydes Using the Acid Enhanced Reactivity of Manganese(IV) Oxide
DOI: 10.14469/hpc/6794 Metadata
Created: 2020-02-21 09:22
Last modified: 2021-01-23 16:48
License: Creative Commons: Public Domain Dedication 1.0
Funding: (none given)
Co-author: James A. Bull
Description
Copper catalysis enabled the oxidative coupling of aldehydes and sulfinates to form a-sulfonylated adducts. The use of MnO2 with an acidic co-solvent allowed access to a broad range of sulfonylated quaternary aldehydes. Derivatisation of the aldehyde allowed access complex derivatives. The mechanism is proposed to be a dual ionic/radical pathway.
Members
| DOI | Description |
|---|---|
| 10.14469/hpc/6800 | Sulfinate Salts |
| 10.14469/hpc/6801 | Sulfinate Salt Scope - Scheme 2 |
| 10.14469/hpc/6802 | Aldehyde Scope - Scheme 3 |
| 10.14469/hpc/6803 | Derivatisation - Scheme 4 |
Associated DOIs
| Current dataset ... | DOI | Description |
|---|---|---|
| References | 10.1039/d0cc01576h | DOI for this work 'Copper catalysed oxidative a-sulfonylation of branched aldehydes using the acid enhanced reactivity of manganese(IV) oxide' published in ChemComm |